An Eco-Friendly Approach to the Control of Pathogenic Microbes and Anopheles stephensi Malarial Vector Using Magnesium Oxide Nanoparticles (Mg-NPs) Fabricated by Penicillium chrysogenum

The discovery of eco-friendly, rapid, and cost-effective compounds to control diseases caused by microbes and insects are the main challenges. Herein, the magnesium oxide nanoparticles (MgO-NPs) are successfully fabricated by harnessing the metabolites secreted by Penicillium chrysogenum. The fabricated MgO-NPs were characterized using UV-Vis, XRD, TEM, DLS, EDX, FT-IR, and XPS analyses. Data showed the successful formation of crystallographic, spherical, well-dispersed MgO-NPs with sizes of 7–40 nm at a maximum wavelength of 250 nm. The EDX analysis confirms the presence of Mg and O ions as the main components with weight percentages of 13.62% and 7.76%, respectively. The activity of MgO-NPs as an antimicrobial agent was investigated against pathogens Staphylococcus aureus, Bacillus subtilis, Pseudomonas aeruginosa, Escherichia coli, and Candida albicans, and exhibited zone of inhibitions of 12.0 ± 0.0, 12.7 ± 0.9, 23.3 ± 0.8, 17.7 ± 1.6, and 14.7 ± 0.6 mm respectively, at 200 µg mL⁻¹. The activity is decreased by decreasing the MgO-NPs concentration. The biogenic MgO-NPs exhibit high efficacy against different larvae instar and pupa of Anopheles stephensi, with LC50 values of 12.5–15.5 ppm for I–IV larvae instar and 16.5 ppm for the pupa. Additionally, 5 mg/cm² of MgO-NPs showed the highest protection percentages against adults of Anopheles stephensi, with values of 100% for 150 min and 67.6% ± 1.4% for 210 min.     

Off-line optimization and control for real time integration of a three-phase hydrogenation catalytic reactor

In order to develop and test the integration procedure, in this paper a real time process integration involving the optimization and control of the process is presented, in this case, with the two-layer approach. The used optimization algorithms were Levenberg–Marquardt and SQP that solve a non-linear least square problem subject to bounds on the variables. The two-layer approach is a hierarchical control structure where an optimization layer calculates the set points and manipulated variables to the advanced controller, which is based on the dynamic matrix control with constraints (QDMC). The non-isothermal dynamic model of the three-phase slurry catalytic reactor with appropriate solution procedure was utilized in this work (Vasco de Toledo, E. C., Santana, P. L., Maciel, M. R. W., & Maciel Filho, R. (2001). Dynamic modeling of a three-phase catalytic slurry reactor. Chemical Engineering Science, 56, 6055–6061). The model consists on mass and heat balance equations for the catalyst particles as well as for the bulk phases of gas and liquid. The model was used to describe the dynamic behavior of hydrogenation reaction of o-cresol to obtain 2-methil-cyclohexanol, in the presence of a catalyst Ni/SiO₂.     

Prediction and optimization of electroplated Ni-based coating composition and thickness using central composite design and artificial neural network

Journal of Applied Electrochemistry - The choice of the electroplating conditions of Ni-based alloys has always been a serious research question. In this study, an artificial neural network based...     

Radiation crosslinking of linear polyethyleneimine-based nanoparticles grafted to poly(glycidyl methacrylate) via trimethylolpropane triacrylate as potential electronic packaging material

Linear polyethyleneimine (L-PEI)-based nanoparticles were synthesized via hydrolysis of poly-2-methyl-2-oxazoline (PMeOx), which was prepared by cationic ring-opening polymerization of the oxazoline five-membered ring. Herein, a kinetic study of the ring-opening polymerization reaction is discussed. The nuclear magnetic resonance spectrum of PMeOx verified the presence of repeating units and terminal groups in the polymer's structure. Molar ratios of PEI and PMeOx were characterized using size exclusion chromatography with low-polydispersity polymer chains as the controlled polymerization reaction. PEI and PMeOx exhibited narrow particle size distribution with hydrodynamic radii of 89 and 67 nm, respectively, as determined via dynamic light scattering analysis. In addition, atomic forces and scanning electron microscopy were used to investigate the topography of the PEI thin films. Poly(glycidyl methacrylate) P(GMA) was grafted onto a PEI chain in the presence of trimethylolpropane triacrylate (TMPTA) as the crosslinking agent to synthesize the P(GMA–PEI–TMPTA) tripolymer via free radical polymerization using gamma irradiation. The thermal characterization of the P(GMA–PEI–TMPTA) tripolymer was conducted using thermogravimetric analysis and differential scanning calorimeter. Generally, the thermal stability of the P(GMA–PEI–TMPTA) tripolymer was improved at low-glycidyl methacrylate concentrations. The prepared tripolymer could be used as effective packaging materials for electronics industries.     

A Model for Incident Tickets Correlation in Network Management

In Information Technology Service Management (ITSM), network management teams typically use an Incident Ticket System (ITS) as a tool to track, troubleshoot, and coordinate the resolution of network incidents that occur during the daily operation of the network. A well organized ITS may positively impact on the efficiency of the incident management process. Nevertheless, in many cases the handling of tickets by the management team is not completely systematic and may be incoherent and inefficient. This way, irrelevant or redundant tickets for the same incident may be issued, thus creating a redundancy in the system that leads to inefficiencies. In this paper, we suggest a model aimed to correlate redundant tickets in order to reduce the information to a single ticket per incident. We validate the proposed correlation model by evaluating it with two datasets taken from a real ticketing system of a telecommunications network company. Using this model as a basis, we also develop and evaluate a methodology that assesses the efficiency of the management team during the process of tickets creation and management. Based on it, we also get some insights on the performance of the different management groups involved in the ticket creation process. These analyses can be leveraged for improving both the management groups functioning and the policies for the tickets’ creation.     

Nonparametric Traversability Estimation in Partially Occluded and Deformable Terrain

Terrain traversability estimation is a fundamental requirement to ensure the safety of autonomous planetary rovers and their ability to conduct long‐term missions. This paper addresses two fundamental challenges for terrain traversability estimation techniques. First, representations of terrain data, which are typically built by the rover's onboard exteroceptive sensors, are often incomplete due to occlusions and sensor limitations. Second, during terrain traversal, the rover‐terrain interaction can cause terrain deformation, which may significantly alter the difficulty of traversal. We propose a novel approach built on Gaussian process (GP) regression to learn, and consequently to predict, the rover's attitude and chassis configuration on unstructured terrain using terrain geometry information only. First, given incomplete terrain data, we make an initial prediction under the assumption that the terrain is rigid, using a learnt kernel function. Then, we refine this initial estimate to account for the effects of potential terrain deformation, using a near‐to‐far learning approach based on multitask GP regression. We present an extensive experimental validation of the proposed approach on terrain that is mostly rocky and whose geometry changes as a result of loads from rover traversals. This demonstrates the ability of the proposed approach to accurately predict the rover's attitude and configuration in partially occluded and deformable terrain.     

Target point‐based path‐following controller for a car‐type vehicle using bounded controls

In this paper, we have studied the control problem of target point‐based path following for car‐type vehicles. This special path‐following task arises from the needs of vision‐based guidance systems, where a given target point located ahead of the vehicle, in the visual range of the camera, must follow a specified path. A solution to this problem is developed through a nonlinear transformation of the path‐following problem into a reference trajectory tracking problem, by modeling the target point as a virtual vehicle. The use of target point complicates the control problem, as the development produces a first‐order nonlinear nonglobally Lipschitz differential equation with finite escape time. This problem is solved by using small control signals. Bounded feedback laws are designed to control the real vehicle's angular acceleration and the virtual vehicle's velocity, to achieve stability. The resulting controller is globally asymptotically stable with respect to the origin, the proof of which is derived from Lyapunov‐based arguments and a bootstrap argument. It is also shown that the use of exponentially convergent observers/differentiators does not affect the stability of the closed‐loop system. The effectiveness of this controller has been illustrated through simulations. Copyright © 2014 John Wiley & Sons, Ltd.     

Opening web applications for third-party development: a service-oriented solution

Web applications are nowadays prevalent software systems in our everyday’s life. A lot of these applications have been developed for end users only. Thus, they are not designed by considering future extensions that would be developed by third parties. One possible and interesting solution for opening these applications for such kind of extension development is to create and deploy Web services starting from these applications. In this paper, we present a method and a tool for semiautomatically creating Web service implementations from applications having Web interfaces. The proposed method generates operations that are published in Web services for each functionality provided by a Web application. In addition, it generates new operations starting from Web interfaces. Our approach goes further in the creation of services by generating executable orchestrations, as BPEL processes, starting from navigations in the Web interfaces of these applications and by providing BPMN choreography specifications starting from the collaborations between the generated Web services. We implemented and experimented our solution in the migration of three real-world Web applications toward Web service-oriented systems.     

Large-scale linked data integration using probabilistic reasoning and crowdsourcing

We tackle the problems of semiautomatically matching linked data sets and of linking large collections of Web pages to linked data. Our system, ZenCrowd, (1) uses a three-stage blocking technique in order to obtain the best possible instance matches while minimizing both computational complexity and latency, and (2) identifies entities from natural language text using state-of-the-art techniques and automatically connects them to the linked open data cloud. First, we use structured inverted indices to quickly find potential candidate results from entities that have been indexed in our system. Our system then analyzes the candidate matches and refines them whenever deemed necessary using computationally more expensive queries on a graph database. Finally, we resort to human computation by dynamically generating crowdsourcing tasks in case the algorithmic components fail to come up with convincing results. We integrate all results from the inverted indices, from the graph database and from the crowd using a probabilistic framework in order to make sensible decisions about candidate matches and to identify unreliable human workers. In the following, we give an overview of the architecture of our system and describe in detail our novel three-stage blocking technique and our probabilistic decision framework. We also report on a series of experimental results on a standard data set, showing that our system can achieve a 95 % average accuracy on instance matching (as compared to the initial 88 % average accuracy of the purely automatic baseline) while drastically limiting the amount of work performed by the crowd. The experimental evaluation of our system on the entity linking task shows an average relative improvement of 14 % over our best automatic approach.     

A model-based survey of alert correlation techniques

As telecommunication networks evolve rapidly in terms of scalability, complexity, and heterogeneity, the efficiency of fault localization procedures and the accuracy in the detection of anomalous behaviors are becoming important factors that largely influence the decision making process in large management companies. For this reason, telecommunication companies are doing a big effort investing in new technologies and projects aimed at finding efficient management solutions. One of the challenging issues for network and system management operators is that of dealing with the huge amount of alerts generated by the managed systems and networks. In order to discover anomalous behaviors and speed up fault localization processes, alert correlation is one of the most popular resources. Although many different alert correlation techniques have been investigated, it is still an active research field. In this paper, a survey of the state of the art in alert correlation techniques is presented. Unlike other authors, we consider that the correlation process is a common problem for different fields in the industry. Thus, we focus on showing the broad influence of this problem. Additionally, we suggest an alert correlation architecture capable of modeling current and prospective proposals. Finally, we also review some of the most important commercial products currently available.